Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models.
1. Introduction - p. xvii 2. Part I: Phase Diagrams and Thermodynamics - p. xviii 3. 1: Introduction - p. xviii 4. 2: Thermodynamics Fundamentals - p. 8 5. 3: The Gibbs Phase Rule - p. 31 6. 4: Fundamentals of the Thermodynamics of Solutions - p. 40 7. 5: Thermodynamic Origin of Phase Diagrams - p. 52 8. 6: Ternary Temperature-Composition Phase Diagrams - p. 84 9. 7: General Phase Diagram Sections - p. 102 10. 8: Equilibrium and Scheil-Gulliver Solidification - p. 131 11. 9: Paraequilibrium Phase Diagrams and Minimum Gibbs Energy Diagrams - p. 148 12. 10: Second-Order and Higher-Order Transitions - p. 158 13. 11: Phase Diagrams of Systems With an Aqueous Phase - p. 164 14. 12: Bibliography on Phase Diagrams - p. 182 15. Part II: Thermodynamic Modeling of Solutions - p. 185 16. 13: Introduction - p. 185 17. 14: Single-Lattice Random-Mixing (Bragg-Williams—BW) Models - p. 191 18. 15: Multiple-Sublattice Random-Mixing (Bragg-Williams—BW) Models - p. 227 19. 16: Single-Lattice Models With Short-Range Ordering (SRO) - p. 252 20. 17: Modeling Short-Range Ordering With Two Sublattices - p. 294 21. 18: Some Applications - p. 318 22. Exercises - p. 350 23. 19: Exercises With Solutions - p. 350 24. Index - p. 377
Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models.
1. Introduction - p. xvii 2. Part I: Phase Diagrams and Thermodynamics - p. xviii 3. 1: Introduction - p. xviii 4. 2: Thermodynamics Fundamentals - p. 8 5. 3: The Gibbs Phase Rule - p. 31 6. 4: Fundamentals of the Thermodynamics of Solutions - p. 40 7. 5: Thermodynamic Origin of Phase Diagrams - p. 52 8. 6: Ternary Temperature-Composition Phase Diagrams - p. 84 9. 7: General Phase Diagram Sections - p. 102 10. 8: Equilibrium and Scheil-Gulliver Solidification - p. 131 11. 9: Paraequilibrium Phase Diagrams and Minimum Gibbs Energy Diagrams - p. 148 12. 10: Second-Order and Higher-Order Transitions - p. 158 13. 11: Phase Diagrams of Systems With an Aqueous Phase - p. 164 14. 12: Bibliography on Phase Diagrams - p. 182 15. Part II: Thermodynamic Modeling of Solutions - p. 185 16. 13: Introduction - p. 185 17. 14: Single-Lattice Random-Mixing (Bragg-Williams—BW) Models - p. 191 18. 15: Multiple-Sublattice Random-Mixing (Bragg-Williams—BW) Models - p. 227 19. 16: Single-Lattice Models With Short-Range Ordering (SRO) - p. 252 20. 17: Modeling Short-Range Ordering With Two Sublattices - p. 294 21. 18: Some Applications - p. 318 22. Exercises - p. 350 23. 19: Exercises With Solutions - p. 350 24. Index - p. 377
