Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology.
This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.
* Unique contributions brings readers up-to-date on new research and application developments
* Figures and tables supplement comprehensive topics
* Extensive author and subject index
1. Chapter 53: Selective introduction of solid acid sites into the mesopore surface of non-acidic USY zeolite by aluminum insertion 2. Chapter 54: Influence of zirconium on the crystallisation kinetics of ETS-4 molecular sieves 3. Chapter 55: Synthesis of silver nanoparticles within ordered CMK-3 mesoporous carbon 4. Chapter 56: Supercritical carbon dioxide as medium for the formation of gold nanoparticles into MCM-41 and its catalytic activity 5. Chapter 57: 3D Design of self-assembled nanoporous colloids 6. Chapter 58: Fabrication and porosity control of mesoporous polycarbosilane from SBA-15 templated polymethylsilane 7. Chapter 59: Structuration of organo-minerals: nanohybrid materials resulting from the incorporation of alcohols in the tunnels of palygorskite 8. Chapter 60: Synthesis and characterization of mesostructured alloys with controlled compositions 9. Chapter 61: One-pot synthesis and characterization of high surface area perovskite-type BaTiO3 with mesoporous texture 10. Chapter 62: Novel non-surfactant pathway to controllable micro/mesoporous bimodal xerogels 11. Chapter 63: An ultrafiltration membrane, prepared with MSU-type mesoporous silica: preparation and specific filtration behavior 12. Chapter 64: Synthesis and adsorption properties of FDU-1 silica with carbon deposited in mesopores 13. IX. Porous Polymers and Polymer/Inorganic Nanocomposites 14. Chapter 65: Flexible coordination polymers as novel porous materials 15. Chapter 66: Conducting polymer and carbon mesoporous structures by electrochemical syntheses 16. Chapter 67: Preparation and electrorheological property of conducting copolyaniline/MCM-41 nanocomposite 17. Chapter 68: Synthesis and characterization of intercalated mesostructured PANI/V2O5 18. Chapter 69: Synthesis, characterization and application of poly (butyl acrylate -co-methyl methacrylate)/clay nanocomposites via emulsion polymerization 19. X. Mesoporous Carbons 20. Chapter 70: Mesoporous carbon prepared by nanocasting of MCM-41 and MCM-48 nanospheres 21. Chapter 71: SBA-15 templated-ordered mesoporous carbon: effect of SBA-15 microporosity 22. Chapter 72: Well-ordered cubic mesoporous carbon with Im3m symmetry 23. Chapter 73: Carbonization of sucrose in the presence of zeolite: control over pore structure and morphology 24. Chapter 74: Synthesis of hollow spherical mesoporous N-doped carbon materials with graphitic framework 25. Chapter 75: Porous N-doped carbon with various hollow-cored morphologies nanocast using zeolite templates via chemical vapour deposition 26. Chapter 76: Pitch-based carbons synthesized by using silica colloids and ordered mesoporous silica particles as templates 27. Chapter 77: Electrical double-layer capacitive properties of colloidal crystal-templated nanoporous carbons 28. Chapter 78: Generating selective adsorptive sites on activated carbon 29. Chapter 79: Synthesis, characterization and hydrogen storage on ordered carbon adsorbents 30. Chapter 80: Monitoring the preparation of spherical activated carbon from sulfonated styrene-divinylbenzene copolymer 31. XI. Adsorption and Characterization of Nanomaterials 32. Chapter 81: The sorption of butanes over carbon nanotubes 33. Chapter 82: Adsorption of Benzene on MCM-41-type Material: A QM/MM Study 34. Chapter 83: Adsorption of amino acid on mesoporous molecular sieves 35. Chapter 84: Adsorption of lysozyme over mesoporous carbons with various pore diameters 36. Chapter 85: Competition between organics adsorbed in mesoporous MCM-41 materials: predictions for heterogeneous catalysis 37. Chapter 86: Famotidine drug adsorption on carboxylic acid functionalized ordered SBA-15 mesoporous silica 38. Chapter 87: Acidity and sorption properties of nano-sized mesoporous aluminosilicate materials 39. Chapter 88: Pore size characterization of mesoporous materials by a thermodynamic approach: A curvature-dependent solid-fluid potential 40. Chapter 89: Characterization of pore structure of copolymer-templated periodic mesoporous organosilicas 41. Chapter 90: Influence of the wall heterogeneity on the layering transition in cylindrical pores 42. Chapter 91: Melting of krypton monolayers adsorbed on carbon nanopores 43. Chapter 92: Determination of cardiac troponin I by anodic stripping voltammetry at SBA-15 modified carbon paste electrode 44. Chapter 93: Spectroscopic characterization and catalytic performances of Iron substituted three dimensional cubic SBA-1 and KIT-5 mesoporous molecular sieves 45. Chapter 94: Photoluminescence property of [Eu(bpy)2]3+ dispersed in mesoporous materials SBA-15 46. Chapter 95: Microemulsion templated mesoporous silica: characterisation via small angle x-ray scattering and stability in aqueous buffers 47. Chapter 96: Dynamics of guests in microporous coordination polymers studied by solid state NMR and X-ray analysis 48. XII. Catalytic Applications of Nanoporous Materials 49. Chapter 97: Molecular designed vanadia–titania supported SBA-15 for the oxidative dehydrogenation of isobutane and propane 50. Chapter 98: Excited-state deprotonation dynamics of 2-naphthol in NaX nanoreactors 51. Chapter 99: Catalytic performance of noble metals supported on Al2O3-modified MCM-41 for thiophene hydrodesulfurization 52. Chapter 100: Hydrodesulfurization of thiophene over cobalt and molybdenum sulfides supported on MCM-41 materials 53. Chapter 101: Oxygen-free dehydroaromatization of methane over Mo-based catalysts supported on MCM-41 and MCM-22 54. Chapter 102: Immobilized molybdovanadophosphoric acids on SBA-15 for selective oxidation of alkenes 55. Chapter 103: Introduction of tin into mesoporous molecular sieves for oxidation of adamantanone 56. Chapter 104: Vapor-phase photocatalytic oxidation of volatile organic compounds over novel uranyl-anchored MCM-41 heterogeneous catalyst 57. Chapter 105: Metathesis of linear α-olefins with MoO3 supported on MCM-41 catalyst 58. Chapter 106: t-Butylation of 1,2-dihydroxybenzene over mesoporous solid acid catalysts 59. Chapter 107: Evaluation of MY Zeolites (M= Pt, Pd, Ni) in the Transalkylation of Trimethylbenzene with Benzene 60. Chapter 108: New catalysts for Diels-Alder reaction of myrcene and acrolein prepared by solid-state interaction of MCM-41 silica and ZnCl2 61. Chapter 109: Diels-Alder cycloadditions of single-wall carbon nanotubes with electron-rich dienes: a theoretical study 62. Chapter 110: Fischer-Tropsch synthesis over Co/SiMCM-41 and Co/SiO2 materials: The role of support at different cobalt loadings 63. Chapter 111: Metathesis of 1-hexene over MoO3 and Re2O7 supported on mesostructured γ-Al2O3 prepared with cationic surfactants 64. Chapter 112: The catalytic epimerization of sugars over immobilized heptamolybdate: comparison of resins, layered double hydroxides and mesoporous silica as support 65. Chapter 113: Immobilization of Mn(salen) complex on aluminum-containing mesoporous materials by microwave heating for epoxidation of styrene 66. Chapter 114: Catalytic formation of acetic anhydride over tungstophosphoric acid-impregnated SBA-15 mesoporous materials 67. Chapter 115: Synthesis of vitamin K3 over mesoporous Zr-MCM-41 molecular sieves 68. Chapter 116: A mild, eco-friendly and efficient zeolite catalyzed synthesis of vibrindole A and bis(indolyl)methanes 69. XIII. Environmental Applications of Nanoporous Materials 70. Chapter 117: A high capacity, water tolerant adsorbent for CO2: diethanolamine supported on pore-expanded MCM-41 71. Chapter 118: Amine-functionalised mesoporous silicas as CO2 adsorbents 72. Chapter 119: Functionalized mesoporous SBA-15 silica molecular sieves with mercaptopropyl groups: Preparation, characterization and application as adsorbents 73. Chapter 120: New efficient Al-containing SBA-15 materials for removing nitrosamines in mild conditions 74. Chapter 121: Functionalization of silica by in-situ grafting hydrotalcite 75. Chapter 122: Synthesis and characterization of mesoporous silicas functionalized by thiol groups, and application as sorbents for mercury (II) 76. Chapter 123: Microporous titanosilicate ETS-10 for the removal of divalent heavy metals 77. Chapter 124: Microwave synthesis of FDU-1 silica with incorporated humic acid and its application for adsorption of Cd2+ from aqueous solutions 78. Chapter 125: Preparation of high surface area mesoporous activated carbon fiber and its adsorption properties of sulfides from light oil 79. Chapter 126: The recovery of rhodium ions at ultra-low concentrations using nanostructured adsorbents 80. Author Index 81. Subject Index 82. Studies in Surface Science and Catalysis
Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology.
This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.
* Unique contributions brings readers up-to-date on new research and application developments
* Figures and tables supplement comprehensive topics
* Extensive author and subject index
1. Chapter 53: Selective introduction of solid acid sites into the mesopore surface of non-acidic USY zeolite by aluminum insertion 2. Chapter 54: Influence of zirconium on the crystallisation kinetics of ETS-4 molecular sieves 3. Chapter 55: Synthesis of silver nanoparticles within ordered CMK-3 mesoporous carbon 4. Chapter 56: Supercritical carbon dioxide as medium for the formation of gold nanoparticles into MCM-41 and its catalytic activity 5. Chapter 57: 3D Design of self-assembled nanoporous colloids 6. Chapter 58: Fabrication and porosity control of mesoporous polycarbosilane from SBA-15 templated polymethylsilane 7. Chapter 59: Structuration of organo-minerals: nanohybrid materials resulting from the incorporation of alcohols in the tunnels of palygorskite 8. Chapter 60: Synthesis and characterization of mesostructured alloys with controlled compositions 9. Chapter 61: One-pot synthesis and characterization of high surface area perovskite-type BaTiO3 with mesoporous texture 10. Chapter 62: Novel non-surfactant pathway to controllable micro/mesoporous bimodal xerogels 11. Chapter 63: An ultrafiltration membrane, prepared with MSU-type mesoporous silica: preparation and specific filtration behavior 12. Chapter 64: Synthesis and adsorption properties of FDU-1 silica with carbon deposited in mesopores 13. IX. Porous Polymers and Polymer/Inorganic Nanocomposites 14. Chapter 65: Flexible coordination polymers as novel porous materials 15. Chapter 66: Conducting polymer and carbon mesoporous structures by electrochemical syntheses 16. Chapter 67: Preparation and electrorheological property of conducting copolyaniline/MCM-41 nanocomposite 17. Chapter 68: Synthesis and characterization of intercalated mesostructured PANI/V2O5 18. Chapter 69: Synthesis, characterization and application of poly (butyl acrylate -co-methyl methacrylate)/clay nanocomposites via emulsion polymerization 19. X. Mesoporous Carbons 20. Chapter 70: Mesoporous carbon prepared by nanocasting of MCM-41 and MCM-48 nanospheres 21. Chapter 71: SBA-15 templated-ordered mesoporous carbon: effect of SBA-15 microporosity 22. Chapter 72: Well-ordered cubic mesoporous carbon with Im3m symmetry 23. Chapter 73: Carbonization of sucrose in the presence of zeolite: control over pore structure and morphology 24. Chapter 74: Synthesis of hollow spherical mesoporous N-doped carbon materials with graphitic framework 25. Chapter 75: Porous N-doped carbon with various hollow-cored morphologies nanocast using zeolite templates via chemical vapour deposition 26. Chapter 76: Pitch-based carbons synthesized by using silica colloids and ordered mesoporous silica particles as templates 27. Chapter 77: Electrical double-layer capacitive properties of colloidal crystal-templated nanoporous carbons 28. Chapter 78: Generating selective adsorptive sites on activated carbon 29. Chapter 79: Synthesis, characterization and hydrogen storage on ordered carbon adsorbents 30. Chapter 80: Monitoring the preparation of spherical activated carbon from sulfonated styrene-divinylbenzene copolymer 31. XI. Adsorption and Characterization of Nanomaterials 32. Chapter 81: The sorption of butanes over carbon nanotubes 33. Chapter 82: Adsorption of Benzene on MCM-41-type Material: A QM/MM Study 34. Chapter 83: Adsorption of amino acid on mesoporous molecular sieves 35. Chapter 84: Adsorption of lysozyme over mesoporous carbons with various pore diameters 36. Chapter 85: Competition between organics adsorbed in mesoporous MCM-41 materials: predictions for heterogeneous catalysis 37. Chapter 86: Famotidine drug adsorption on carboxylic acid functionalized ordered SBA-15 mesoporous silica 38. Chapter 87: Acidity and sorption properties of nano-sized mesoporous aluminosilicate materials 39. Chapter 88: Pore size characterization of mesoporous materials by a thermodynamic approach: A curvature-dependent solid-fluid potential 40. Chapter 89: Characterization of pore structure of copolymer-templated periodic mesoporous organosilicas 41. Chapter 90: Influence of the wall heterogeneity on the layering transition in cylindrical pores 42. Chapter 91: Melting of krypton monolayers adsorbed on carbon nanopores 43. Chapter 92: Determination of cardiac troponin I by anodic stripping voltammetry at SBA-15 modified carbon paste electrode 44. Chapter 93: Spectroscopic characterization and catalytic performances of Iron substituted three dimensional cubic SBA-1 and KIT-5 mesoporous molecular sieves 45. Chapter 94: Photoluminescence property of [Eu(bpy)2]3+ dispersed in mesoporous materials SBA-15 46. Chapter 95: Microemulsion templated mesoporous silica: characterisation via small angle x-ray scattering and stability in aqueous buffers 47. Chapter 96: Dynamics of guests in microporous coordination polymers studied by solid state NMR and X-ray analysis 48. XII. Catalytic Applications of Nanoporous Materials 49. Chapter 97: Molecular designed vanadia–titania supported SBA-15 for the oxidative dehydrogenation of isobutane and propane 50. Chapter 98: Excited-state deprotonation dynamics of 2-naphthol in NaX nanoreactors 51. Chapter 99: Catalytic performance of noble metals supported on Al2O3-modified MCM-41 for thiophene hydrodesulfurization 52. Chapter 100: Hydrodesulfurization of thiophene over cobalt and molybdenum sulfides supported on MCM-41 materials 53. Chapter 101: Oxygen-free dehydroaromatization of methane over Mo-based catalysts supported on MCM-41 and MCM-22 54. Chapter 102: Immobilized molybdovanadophosphoric acids on SBA-15 for selective oxidation of alkenes 55. Chapter 103: Introduction of tin into mesoporous molecular sieves for oxidation of adamantanone 56. Chapter 104: Vapor-phase photocatalytic oxidation of volatile organic compounds over novel uranyl-anchored MCM-41 heterogeneous catalyst 57. Chapter 105: Metathesis of linear α-olefins with MoO3 supported on MCM-41 catalyst 58. Chapter 106: t-Butylation of 1,2-dihydroxybenzene over mesoporous solid acid catalysts 59. Chapter 107: Evaluation of MY Zeolites (M= Pt, Pd, Ni) in the Transalkylation of Trimethylbenzene with Benzene 60. Chapter 108: New catalysts for Diels-Alder reaction of myrcene and acrolein prepared by solid-state interaction of MCM-41 silica and ZnCl2 61. Chapter 109: Diels-Alder cycloadditions of single-wall carbon nanotubes with electron-rich dienes: a theoretical study 62. Chapter 110: Fischer-Tropsch synthesis over Co/SiMCM-41 and Co/SiO2 materials: The role of support at different cobalt loadings 63. Chapter 111: Metathesis of 1-hexene over MoO3 and Re2O7 supported on mesostructured γ-Al2O3 prepared with cationic surfactants 64. Chapter 112: The catalytic epimerization of sugars over immobilized heptamolybdate: comparison of resins, layered double hydroxides and mesoporous silica as support 65. Chapter 113: Immobilization of Mn(salen) complex on aluminum-containing mesoporous materials by microwave heating for epoxidation of styrene 66. Chapter 114: Catalytic formation of acetic anhydride over tungstophosphoric acid-impregnated SBA-15 mesoporous materials 67. Chapter 115: Synthesis of vitamin K3 over mesoporous Zr-MCM-41 molecular sieves 68. Chapter 116: A mild, eco-friendly and efficient zeolite catalyzed synthesis of vibrindole A and bis(indolyl)methanes 69. XIII. Environmental Applications of Nanoporous Materials 70. Chapter 117: A high capacity, water tolerant adsorbent for CO2: diethanolamine supported on pore-expanded MCM-41 71. Chapter 118: Amine-functionalised mesoporous silicas as CO2 adsorbents 72. Chapter 119: Functionalized mesoporous SBA-15 silica molecular sieves with mercaptopropyl groups: Preparation, characterization and application as adsorbents 73. Chapter 120: New efficient Al-containing SBA-15 materials for removing nitrosamines in mild conditions 74. Chapter 121: Functionalization of silica by in-situ grafting hydrotalcite 75. Chapter 122: Synthesis and characterization of mesoporous silicas functionalized by thiol groups, and application as sorbents for mercury (II) 76. Chapter 123: Microporous titanosilicate ETS-10 for the removal of divalent heavy metals 77. Chapter 124: Microwave synthesis of FDU-1 silica with incorporated humic acid and its application for adsorption of Cd2+ from aqueous solutions 78. Chapter 125: Preparation of high surface area mesoporous activated carbon fiber and its adsorption properties of sulfides from light oil 79. Chapter 126: The recovery of rhodium ions at ultra-low concentrations using nanostructured adsorbents 80. Author Index 81. Subject Index 82. Studies in Surface Science and Catalysis
