Advances in Heterocyclic Chemistry, Volume 138, the latest release in this definitive series on the field of heterocyclic chemistry, combines descriptive synthetic chemistry and mechanistic insights to yield an understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds. Topics in this new release include The Paal Knorr reaction in Heterocyclic Chemistry, Synthesis and Applications of Heterocyclic Sulfoximines, Recent advances in the synthesis of 4H-chromen-4-ones (2012-2021), Recent Developments in the Chemistry of Heteroporphyrins and Heterocarbaporphyrins, The Chemistry of 1,4-Dihydropyrrolo[3,2-b]pyrroles, and more.
1. 1 Introduction - p. 63 2. 2 Physical properties of sulfoximines - p. 65 3. 3 Exocyclic sulfoximine heterocycles - p. 64 4. 4 Endocyclic sulfoximine heterocycles - p. 104 5. 5 Conclusion - p. 149 6. References - p. 151 7. Chapter Three: Recent advances in the synthesis of 4H-chromen-4-ones (2012 − 2021) - p. 159 8. Abstract - p. 160 9. Abbreviations - p. 160 10. 1 Introduction - p. 161 11. 2 Synthesis of 2,3-unsubstituted 4H-chromen-4-ones - p. 163 12. 3 Synthesis of 2-substituted 4H-chromen-4-ones - p. 166 13. 4 Synthesis of 3-substituted 4H-chromen-4-ones - p. 187 14. 5 Synthesis of 2,3-disubstituted 4H-chromen-4-ones - p. 204 15. 6 Conclusions - p. 225 16. Acknowledgments - p. 225 17. References - p. 225 18. Chapter Four: Recent developments in the chemistry of heteroporphyrins and heterocarbaporphyrins - p. 243 19. Abstract - p. 243 20. 1 Introduction - p. 244 21. 2 meso-Unsubstituted mono- and diheteroporphyrins and related annulated systems - p. 246 22. 3 meso-Substituted mono- and diheteroporphyrins and their coordination complexes - p. 265 23. 4 meso-Substituted heteroporphyrins with fused aromatic rings - p. 264 24. 5 Telluraporphyrins and porphyrinoids derived therefrom - p. 267 25. 6 Carbazole-derived heteroporphyrins and related systems - p. 272 26. 7 Tetraoxa-, tetrathia- and tetraselenaporphyrin dications and related systems - p. 276 27. 8 Phosphaporphyrins - p. 280 28. 9 Silaporphyrins - p. 283 29. 10 Carbaporphyrinoid systems - p. 284 30. 11 Heterocarbaporphyrins - p. 285 31. 12 Heteroazuliporphyrins - p. 293 32. 13 Heterobenziporphyrins - p. 313 33. 14 Hetero-N-confused porphyrins and X-confused heteroporphyrins - p. 312 34. 15 Miscellaneous heteroporphyrinoid systems - p. 322 35. 16 Contracted heteroporphyrins - p. 321 36. 17 Conclusions - p. 326 37. Acknowledgments - p. 327 38. References - p. 327 39. Chapter Five: The chemistry of 1,4-dihydropyrrolo[3,2-b]pyrroles - p. 335 40. Index - p. 409
Advances in Heterocyclic Chemistry, Volume 138, the latest release in this definitive series on the field of heterocyclic chemistry, combines descriptive synthetic chemistry and mechanistic insights to yield an understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds. Topics in this new release include The Paal Knorr reaction in Heterocyclic Chemistry, Synthesis and Applications of Heterocyclic Sulfoximines, Recent advances in the synthesis of 4H-chromen-4-ones (2012-2021), Recent Developments in the Chemistry of Heteroporphyrins and Heterocarbaporphyrins, The Chemistry of 1,4-Dihydropyrrolo[3,2-b]pyrroles, and more.
1. 1 Introduction - p. 63 2. 2 Physical properties of sulfoximines - p. 65 3. 3 Exocyclic sulfoximine heterocycles - p. 64 4. 4 Endocyclic sulfoximine heterocycles - p. 104 5. 5 Conclusion - p. 149 6. References - p. 151 7. Chapter Three: Recent advances in the synthesis of 4H-chromen-4-ones (2012 − 2021) - p. 159 8. Abstract - p. 160 9. Abbreviations - p. 160 10. 1 Introduction - p. 161 11. 2 Synthesis of 2,3-unsubstituted 4H-chromen-4-ones - p. 163 12. 3 Synthesis of 2-substituted 4H-chromen-4-ones - p. 166 13. 4 Synthesis of 3-substituted 4H-chromen-4-ones - p. 187 14. 5 Synthesis of 2,3-disubstituted 4H-chromen-4-ones - p. 204 15. 6 Conclusions - p. 225 16. Acknowledgments - p. 225 17. References - p. 225 18. Chapter Four: Recent developments in the chemistry of heteroporphyrins and heterocarbaporphyrins - p. 243 19. Abstract - p. 243 20. 1 Introduction - p. 244 21. 2 meso-Unsubstituted mono- and diheteroporphyrins and related annulated systems - p. 246 22. 3 meso-Substituted mono- and diheteroporphyrins and their coordination complexes - p. 265 23. 4 meso-Substituted heteroporphyrins with fused aromatic rings - p. 264 24. 5 Telluraporphyrins and porphyrinoids derived therefrom - p. 267 25. 6 Carbazole-derived heteroporphyrins and related systems - p. 272 26. 7 Tetraoxa-, tetrathia- and tetraselenaporphyrin dications and related systems - p. 276 27. 8 Phosphaporphyrins - p. 280 28. 9 Silaporphyrins - p. 283 29. 10 Carbaporphyrinoid systems - p. 284 30. 11 Heterocarbaporphyrins - p. 285 31. 12 Heteroazuliporphyrins - p. 293 32. 13 Heterobenziporphyrins - p. 313 33. 14 Hetero-N-confused porphyrins and X-confused heteroporphyrins - p. 312 34. 15 Miscellaneous heteroporphyrinoid systems - p. 322 35. 16 Contracted heteroporphyrins - p. 321 36. 17 Conclusions - p. 326 37. Acknowledgments - p. 327 38. References - p. 327 39. Chapter Five: The chemistry of 1,4-dihydropyrrolo[3,2-b]pyrroles - p. 335 40. Index - p. 409