Nanomaterials via Single-Source Precursors: Synthesis, Processing and Applications presents recent results and overviews of synthesis, processing, characterization and applications of advanced materials for energy, electronics, biomedicine, sensors and aerospace. A variety of processing methods (vapor, liquid and solid-state) are covered, along with materials, including metals, oxides, semiconductor, sulfides, selenides, nitrides, and carbon-based materials. Production of quantum dots, nanoparticles, thin films and composites are described by a collection of international experts. Given the ability to customize the phase, morphology, and properties of target materials, this “rational approach to synthesis and processing is a disruptive technology for electronic, energy, structural and biomedical (nano)materials and devices.
The use of single-source chemical precursors for materials processing technology allows for intimate elemental mixing and hence production of complex materials at temperatures well below traditional physical methods and those involving direct combination of elements. The use of lower temperatures enables thin-film deposition on lightweight polymer substrates and reduces damage to complex devices structures such as used in power, electronics and sensors.
1. Nanomaterials via Single-Source Precursors - p. Page i 2. Cover - p. Page i 3. Front Matter - p. Page i 4. Table of Contents - p. Page iii 5. Copyright - p. Page iv 6. Dedication - p. Page v 7. Contributors - p. Page v 8. Preface - p. Page vi 9. List of Illustrations - p. Page xi 10. List of Tables - p. Page xii 11. Chapter 1 : Precursor design and impact of structure on the fabrication of materials - p. Page xii 12. Chapter 2 : Structural studies of main group organometallic single-source precursors for MOCVD - p. Page 44 13. Chapter 3 : Dithiocarbamate complexes containing the pyrrole moiety for synthesis of sulfides - p. Page 94 14. Chapter 4 : Theoretical studies of gas-phase decomposition of single-source precursors - p. Page 118 15. Chapter 5 : Semiconductor clusters and their use as precursors to nanomaterials - p. Page 154 16. Chapter 6 : Chalcogenoethers as convenient synthons for low-temperature solution-phase synthesis of metal chalcogenide nanocrystals - p. Page 194 17. Chapter 7 : Synthesis of lanthanide chalcogenide nanoparticles - p. Page 214 18. Chapter 8 : Organometallic single-source precursors to zinc oxide-based nanomaterials - p. Page 239 19. Chapter 9 : Nickel chalcogenide thin films and nanoparticles from molecular single-source precursors - p. Page 274 20. Chapter 10 : Group 15/16 single-source precursors for energy materials - p. Page 302 21. Chapter 11 : Single-source precursors for main group metal sulfides and solar cell applications - p. Page 348 22. Chapter 12 : Fabrication and catalytic applications of first row-transition metal and mixed-metal chalcogenides synthesized from single-source precursors - p. Page 381 23. Chapter 13 : Single-source heterometallic precursors to MOCVD PdCu alloy films for energy and catalysis applications - p. Page 441 24. Chapter 14 : Synthesis of nitrogen-doped carbons from single-source precursors by solution plasma - p. Page 468 25. Chapter 15 : Zinc acetate amine complexes: Single-source precursors to zinc oxide films and nanoparticles; the influence of amines on photocatalysis - p. Page 500 26. Chapter 16 : Coinage metal chalcogenides via single-source precursors - p. Page 524 27. Chapter 17 : Commercialization of single-source precursors: Applications, intellectual property, and technology transfer - p. Page 558 28. Index - p. Page 591
Nanomaterials via Single-Source Precursors: Synthesis, Processing and Applications presents recent results and overviews of synthesis, processing, characterization and applications of advanced materials for energy, electronics, biomedicine, sensors and aerospace. A variety of processing methods (vapor, liquid and solid-state) are covered, along with materials, including metals, oxides, semiconductor, sulfides, selenides, nitrides, and carbon-based materials. Production of quantum dots, nanoparticles, thin films and composites are described by a collection of international experts. Given the ability to customize the phase, morphology, and properties of target materials, this “rational approach to synthesis and processing is a disruptive technology for electronic, energy, structural and biomedical (nano)materials and devices.
The use of single-source chemical precursors for materials processing technology allows for intimate elemental mixing and hence production of complex materials at temperatures well below traditional physical methods and those involving direct combination of elements. The use of lower temperatures enables thin-film deposition on lightweight polymer substrates and reduces damage to complex devices structures such as used in power, electronics and sensors.
1. Nanomaterials via Single-Source Precursors - p. Page i 2. Cover - p. Page i 3. Front Matter - p. Page i 4. Table of Contents - p. Page iii 5. Copyright - p. Page iv 6. Dedication - p. Page v 7. Contributors - p. Page v 8. Preface - p. Page vi 9. List of Illustrations - p. Page xi 10. List of Tables - p. Page xii 11. Chapter 1 : Precursor design and impact of structure on the fabrication of materials - p. Page xii 12. Chapter 2 : Structural studies of main group organometallic single-source precursors for MOCVD - p. Page 44 13. Chapter 3 : Dithiocarbamate complexes containing the pyrrole moiety for synthesis of sulfides - p. Page 94 14. Chapter 4 : Theoretical studies of gas-phase decomposition of single-source precursors - p. Page 118 15. Chapter 5 : Semiconductor clusters and their use as precursors to nanomaterials - p. Page 154 16. Chapter 6 : Chalcogenoethers as convenient synthons for low-temperature solution-phase synthesis of metal chalcogenide nanocrystals - p. Page 194 17. Chapter 7 : Synthesis of lanthanide chalcogenide nanoparticles - p. Page 214 18. Chapter 8 : Organometallic single-source precursors to zinc oxide-based nanomaterials - p. Page 239 19. Chapter 9 : Nickel chalcogenide thin films and nanoparticles from molecular single-source precursors - p. Page 274 20. Chapter 10 : Group 15/16 single-source precursors for energy materials - p. Page 302 21. Chapter 11 : Single-source precursors for main group metal sulfides and solar cell applications - p. Page 348 22. Chapter 12 : Fabrication and catalytic applications of first row-transition metal and mixed-metal chalcogenides synthesized from single-source precursors - p. Page 381 23. Chapter 13 : Single-source heterometallic precursors to MOCVD PdCu alloy films for energy and catalysis applications - p. Page 441 24. Chapter 14 : Synthesis of nitrogen-doped carbons from single-source precursors by solution plasma - p. Page 468 25. Chapter 15 : Zinc acetate amine complexes: Single-source precursors to zinc oxide films and nanoparticles; the influence of amines on photocatalysis - p. Page 500 26. Chapter 16 : Coinage metal chalcogenides via single-source precursors - p. Page 524 27. Chapter 17 : Commercialization of single-source precursors: Applications, intellectual property, and technology transfer - p. Page 558 28. Index - p. Page 591