Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects.
This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry.
1. Cover image - p. Cover 2. Title page - p. iii 3. Table of Contents - p. iii 4. Copyright - p. iv 5. Dedication - p. v 6. List of contributors - p. xiii 7. About the editor - p. xvii 8. Foreword - p. xix 9. Acknowledgments - p. xxi 10. Chapter 1. Understanding intermediate temperature solid oxide fuel cells - p. 1 11. Chapter 2. Thermodynamics, polarizations, and intermediate temperature solid oxide fuel cell performance - p. 33 12. Chapter 3. Brownmillerite and Aurivillius electrolytes for intermediate temperature solid oxide fuel cell - p. 57 13. Chapter 4. Proton-conducting electrolyte materials - p. 81 14. Chapter 5. Enhancing the ionic conductivity in the ceria-based electrolytes for intermediate temperature solid oxide fuel cells - p. 113 15. Chapter 6. Cermets as anode materials - p. 165 16. Chapter 7. Progress in perovskite anodes for intermediate-temperature solid oxide fuel cells - p. 195 17. Chapter 8. Cathode materials for proton-conducting solid oxide fuel cells - p. 263 18. Chapter 9. Perovskite and layered oxide materials for intermediate temperature solid oxide fuel cells - p. 315 19. Chapter 10. Misfit-layered Ca-cobaltite–based cathodes for intermediate-temperature solid oxide fuel cell - p. 347 20. Chapter 11. Stacking designs and sealing principles for IT-solid oxide fuel cell - p. 379 21. Chapter 12. Interaction of glass-ceramic sealants with solid oxide fuel cell components: thermo-mechanical analysis - p. 411 22. Chapter 13. Intermediate-temperature solid oxide fuel cell fueled by biofuels - p. 427 23. Index - p. 477
Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects.
This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry.
1. Cover image - p. Cover 2. Title page - p. iii 3. Table of Contents - p. iii 4. Copyright - p. iv 5. Dedication - p. v 6. List of contributors - p. xiii 7. About the editor - p. xvii 8. Foreword - p. xix 9. Acknowledgments - p. xxi 10. Chapter 1. Understanding intermediate temperature solid oxide fuel cells - p. 1 11. Chapter 2. Thermodynamics, polarizations, and intermediate temperature solid oxide fuel cell performance - p. 33 12. Chapter 3. Brownmillerite and Aurivillius electrolytes for intermediate temperature solid oxide fuel cell - p. 57 13. Chapter 4. Proton-conducting electrolyte materials - p. 81 14. Chapter 5. Enhancing the ionic conductivity in the ceria-based electrolytes for intermediate temperature solid oxide fuel cells - p. 113 15. Chapter 6. Cermets as anode materials - p. 165 16. Chapter 7. Progress in perovskite anodes for intermediate-temperature solid oxide fuel cells - p. 195 17. Chapter 8. Cathode materials for proton-conducting solid oxide fuel cells - p. 263 18. Chapter 9. Perovskite and layered oxide materials for intermediate temperature solid oxide fuel cells - p. 315 19. Chapter 10. Misfit-layered Ca-cobaltite–based cathodes for intermediate-temperature solid oxide fuel cell - p. 347 20. Chapter 11. Stacking designs and sealing principles for IT-solid oxide fuel cell - p. 379 21. Chapter 12. Interaction of glass-ceramic sealants with solid oxide fuel cell components: thermo-mechanical analysis - p. 411 22. Chapter 13. Intermediate-temperature solid oxide fuel cell fueled by biofuels - p. 427 23. Index - p. 477